19-2 Integrated waste to energy and nutrient production system (IWENPS) for renewable methane production and fertilizer-grade digestate recovery
Thursday, April 28, 2016: 1:25 PM
Key Ballroom 8-11-12 2nd Fl (Hilton Baltimore)
M. Urgun-Demirtas*, Y. Shen, J. Linville, R. Schoene and S. Snyder, Argonne National Laboratory, Lemont, IL, USA
Anaerobic digestion converts organic waste into renewable methane.  Biogas generated from anaerobic digestion has a high concentration of CO2 (35 – 50 %) decreasing its heating value, reducing the likelihood of beneficial use, therefore increasing the risk of fugitive methane emissions.  Furthermore, the available biogas cleanup and upgrading techniques are very cost-intensive for widespread adoption in AD industry. We developed a novel in situ bioprocess where both biogas production and cleanup take place in the same reaction vessel to produce renewable methane.  We use multivalent minerals present in porous biochar, a co-product of biomass pyrolysis, to react in situ with CO2 to form insoluble carbonates.  The porous biochar also adsorbs H2S from the biogas. We deliver a biogas containing > 90% CH4 and < 5 ppb H2S; close to fungibility. The biochar addition also enhances the process stability of the digester thereby boosting methane production rate (~28%).  Analysis of the digestate shows that this process can produce a fertilizer-grade soil amendment with highly desirable amount of macro and micro nutrients (N increase 23%, P increase %30, K increase 4-30X, Ca increase 50%, Mg increase 2-18X). Therefore, this novel process paves a path towards a new paradigm of energy and resource recovery from organic waste, including sludge, food waste, agricultural residues, manure and municipal solid waste. The nationwide adoption of IWENPS can produce a total potential energy of 2.5 billion gasoline gallon equivalents per year and reduce emissions by 6.5 million metric tons of CO2 equivalent per year in the US.